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昆明冶金高等专科学校学报 ›› 2025, Vol. 41 ›› Issue (3): 28-.DOI: 10.3969/j.issn.1009-0479.2025.03.005

• 资源开发与测绘 • 上一篇    下一篇

云南某低品位氧化铅锌矿回转窑还原焙烧工业化研究

  

  1. 1昆明冶金高等专科学校冶金与矿业学院,云南 昆明 650033;2云南金鼎锌业有限公司,云南 兰坪 671400
  • 收稿日期:2024-12-23 出版日期:2025-06-07 发布日期:2025-09-23
  • 作者简介:杨志鸿 (1984-),男,陕西汉中人,副教授,工学硕士,主要从事有色金属冶金与资源回收研究。
  • 基金资助:
    云南省教育厅科研基金项目 “湿法炼锌全流程除杂新技术研究”(202302AB080012)。

Industrial Study on the Reduction Roasting of a Low-Grade Lead-ZincOxide Mine in Yunnan Province Using a Rotary Kiln

  1. 1. Faculty of Metallurgy and Mining Engineering, Kunming Metallurgy College, Kunming 650033, China;2.Yunnan Jinding Zine Industry Co.,Ltd., Lanping 671400,Yunnan, China
  • Received:2024-12-23 Online:2025-06-07 Published:2025-09-23

摘要: 现存某地的氧化铅锌矿具有储量大、品位低、矿物组成复杂、难以发挥经济效益的特性。为研究低品 位氧化锌矿还原挥发的规律,逐一对原料及产品的化学成分、赋存状态、微观形貌进行分析,对还原焙烧过程 的热力学行为进行了探讨。实验探索确定了配矿 (配入 25%的还原煤)、制粒、干燥、还原焙烧、水淬的生产 工艺流程。将还原焙烧过程中挥发的 Zn蒸汽冷却后收集于烟尘中,其中锅炉尘平均含 Zn2949%,表冷尘平均 含 Zn4294%,布袋尘平均含 Zn6093%。采用 XRD对原料和炉渣进行对比分析,结果显示炉渣中的 Zn、Pb物 相消失,表明回转窑还原焙烧工艺可以有效地将原料中 Zn、Pb元素挥发出来。通过物料平衡计算得出该回转窑 还原焙烧工业实验过程中 Zn的总回收率达 9718%、Pb的回收率达 9630%,高效实现了次等资源的有效利用。

关键词: 低品位氧化铅锌矿, 还原焙烧, 回转窑, 回收

Abstract: 'The existing lead-zinc oxide mines in a certain place are characterized by large reserves , lowgrades, complex mineral compositions , and difieulty in exerting economic benelits. To study the reduc-tion and volatilization laws of low-grade zinc oxide ores, the chemical compositions, occurrence states,.and miero-morphologies of raw materials and produets were analyzed one by one, and the thermodynamicbehavior of the reduction roasting process was discussed. The production process flow of ore blending( adding 2596 reduction coal ) , granulation, drying, reduction roasting, and water quenching was deter-mined through experimental exploration. The Zn vapor volatilized during the reduction roasting processwas cooled and collected in the dust, among which the boiler dust contained an average of 29. 49% 2n,the surface-cooled dust contained an average of 42. 94%6 Zn, and the bag dust contained an average of60. 93%6 Zn. XRD was used to conduet comparative analysis on raw materials and slag, and the resultsshowed that the phases of Zn and Pb in the slag disappeared, indicating that the rotary kiln reductionroasting process can elfeetively volatilize Zn and Pb elements from the raw materials. Through materialbalance calculations, it was found that the total recovery rate of Zn reached 97. 18%6 and the reeoveryrate of Ph reached 96. 30%6 during the industrial experiment of rotary kiln reduction roasting, efficientlyachieving the effective utilization of secondary resources.

Key words:  , low-grade lead-zinc oxide ore , reduction roasting, rotary kiln , recovery