欢迎访问昆明冶金高等专科学校学报官方网站,今天是 分享到:

昆明冶金高等专科学校学报 ›› 2023, Vol. 39 ›› Issue (6): 9-.DOI: 10.3969/j.issn.1009-0479.2023.06.002

• 冶金技术与材料 • 上一篇    下一篇

氮掺杂型石墨烯薄膜光学性质研究

战祥浩1,田品2,唐利斌2,于杰田3   

  1. (1.云南经济管理学院通识学院,云南昆明650106;2.昆明物理研究所,云南昆明650221;3.昆明理工大学材料科学与工程学院,云南昆明650500)
  • 收稿日期:2023-08-24 出版日期:2023-12-02 发布日期:2024-03-11
  • 作者简介:战祥浩 (1988-),男,山东日照人,讲师,工学硕士,主要从事先进功能材料研究。
  • 基金资助:
    云南省先进光电探测技术创新团队 (2019YFB2203404)。

Study on the Optical Properties of Nitrogen-Doped Graphene Films

ZHAN Xianghao1, TlAN Pin2, TANG Libin2, YU Jie3   

  1. (1. Faculty of General Education, Yunnan College of Bussiness Management, Kunming 650106, China;2.Kunming Institute of Physics,Kunming 650221, China;3. Ffaculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China)
  • Received:2023-08-24 Online:2023-12-02 Published:2024-03-11

摘要: 以葡萄糖为碳源,2、4、6-三胺基嘧啶为氮源,制备掺杂前驱体后通过真空高温退火,生长得到氮掺杂型石墨烯薄膜,并对生长得到的氮掺杂型石墨烯薄膜进行了各类光电性能表征。通过拉曼表征证实该薄膜是多层石墨烯薄膜,有一定的缺陷,但结晶度较好。XPS表征也证实氮元素成功地掺杂进石墨烯晶格结构中,并以共价键结合。通过透射电镜表征,薄膜表面附着许多20~30nm 量子点,薄膜形态比较致密。UV-Vis吸收光谱测试证实,该掺杂的石墨烯薄膜吸收峰产生一定程度的蓝移,掺杂氣元素后薄膜对可见光整体吸收能力加强。

关键词: 2、4、6-三胺基嘧啶, 葡萄糖, 氮掺杂型石墨烯薄膜, 能隙

Abstract: In this paper, using glucose as carbon source and 2, 4, 6 - triamino-pyrimidine as nitrogensource , nitrogen-doped graphene films were grown by vacuum annealing at high temperature, and variousphotoelectric properties of the grown nitrogen-doped graphene films were characterized. Raman character.ization confirmed that the film is a multilayer graphene film with certain defects but crystallinity is good.XPS characterization also confirmed that nitrogen was successfully doped into the graphene lattice structure and covalent bond, Through transmission electron microscopy , many quantum dots with diameters ol20 ~ 30 nm are attached to the surface of the film , and the film morphology is relatively dense. The UV.Vis absorption spectrum test confirmed that the absorption peak of the doped graphene film produced acertain degree of blue shift , and the overall absorption capacity of the film was enhanced after nitrogen doping.

中图分类号: