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昆明冶金高等专科学校学报 ›› 2023, Vol. 39 ›› Issue (2): 68-.DOI: 10.3969/j.issn.1009-0479.2023.02.009

• 环境保护与化工技术 • 上一篇    下一篇

紫胶树脂的粘流———热硬化转变研究

冀浩博1a ,唐保山2 ,李冬丽1b ,李 坤2 ,马金菊2
  

  1. (1.昆明冶金高等专科学校 a.科学技术处;b.环境与化工学院,云南 昆明 650033;
    2.中国林业科学研究院高原林业研究所,云南 昆明 650233)
  • 收稿日期:2023-04-06 出版日期:2023-04-30 发布日期:2023-11-13
  • 作者简介:冀浩博 (1986-),男,内蒙古乌兰察布人,讲师,工程硕士,主要从事天然产物化学研究。
  • 基金资助:
    云南省教育厅科学研究基金项目:紫胶树脂与聚乳酸的共混改性研究 (2023J1528)

Study on Viscous Flow-Thermal Hardening Transition of Shellac Resin

JI Haobo,TANG Baoshan,LI Dongli,LI Kun,MA Jinju

  

  1. (1a. Division of Science and Technology; 1b. Faculty of Environment and Chemical Engineering, Kunming Metallurgy College, Kunming 650033,China;2. Institute of Highland Forest Science, Chinese Academy of Forestry,Kunming 650233,China)

  • Received:2023-04-06 Online:2023-04-30 Published:2023-11-13

摘要:

为明确紫胶树脂受热后发生的粘流转变过程,以及粘流转变后其特征指标的变化,进而确定紫胶树脂热硬化时间和温度的对应关系。本研究采用热台显微镜观测法监测了紫胶树脂的粘流转变过程,利用差示扫描量热法计算了粘流转变过程热力学参数,测定了粘流转变后的热硬化时间、冷乙醇可溶物和红外光谱中特征峰的变化情况;采用国标紫胶树脂热硬化时间的测定方法测定了不同温度下的热硬化时间,并进行了方程拟合。结果表明,升温速率快,紫胶树脂的粘流转变峰值温度越高,分子的传热效率越低,传热会产生滞后;并且拟合得到了紫胶树脂热硬化时间与温度的关系方程,进行了显著性检验,发现紫胶树脂的热硬化时间随加热温度的升高而降低,其变化趋势按照所拟合方程所示的指数关系递减。

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Abstract:

In order to clarify the viscous flow transition process of shellac resin after heating and the change of its characteristic index after over viscous flow transition, and to determine the corresponding relationship between thermal hardening time and temperature of shellac resin, the viscous flow transition process of shellac resin was monitored by differential scanning calorimetry and heat table microscope observation method, and the thermodynamic parameters of viscous flow transition process were calculated. The changes of thermal hardening time, cold ethanol soluble matter and infrared spectrum after viscous flow transformation were measured, and the thermal hardening time at different temperatures was measured by the method of thermal hardening time of shellac resin, and the equation was fitted. The results show that the faster the heating rate is , the higher the peak temperature of the viscous flow transition of the shellac resin is, the lower the heat transfer efhciency of the molecule is , and the heat transfer will lag, and the viscous lac resinhas a smooth boundary and a water droplet shape. The relation equation between thermal hardening timeand temperature of shellac resin was obtained by fitting, and the significance test was carried out. it wasconcluded that the thermal hardening time of shellac resin decreased with the increase of heating tempera-ture. the trend decreases according to the exponential relation shown in the fitting equation.

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