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Journal of Kunming Metallurgy College ›› 2023, Vol. 39 ›› Issue (2): 10-.DOI: 10.3969/j.issn.1009-0479.2023.02.002

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Prediction of component activities in the ternary molten slags containing titanium oxide

SUN Ying, LIU Zhennan, ZHANG Songyuan, LI U Cong

  

  1.  (1a.Science and Technology Department;  b.  Faculty of Metallurgy and Mining,  Kunming Metallurgy College,Kunming 650033,China; 2. Kunming Key Laboratory of Comprehensive Utilization Resources of Rare and Precious Metals,  Kunming 650033,China)

  • Received:2023-06-20 Online:2023-04-30 Published:2023-11-10

Abstract:

Based on the molecular interaction volume model(MIVM) and the coexistence theory model,the component activities were predicted in the ternary slags Fe0-Mn0-SiOz,Fe0-Mn0-TiOz,Mn0-SiOz-TiOzand Fe0-SiOz-TiOz .In com parison with the experiment data,the total average relative errors of the predicted value by pseudo-multicomponent approach of MIVM were 16%,the total average standard deviations were 0. 062. On the other hand,the total average relative errors of the predicted value by coexistence theory model were 28%,the total average standard deviations were 0.  077. The prediction effect of the pseudo-multicomponent approach of MIVM has better stability and reliability than coexistence theory. the activities of component TiOzwere predicted in the ternary slags Fe0-Mn0TiOz,Mn0-SiOz-TiOzand Fe0-SiOz-TiOz by MIVM,draw its isoactivity curve,the thermodynamic behavior tendency of constituent TiOz in different slag systems was analyzed.

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