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昆明冶金高等专科学校学报 ›› 2022, Vol. 38 ›› Issue (4): 89-.DOI: 10.3969/j.issn.1009-0479.2022.04.014

• 环境保护与化工技术 • 上一篇    下一篇

添加钙法脱硫废水对硫酸按结晶影响

李 锐1,赵 鹏1,张燕玲 1,周微波1,黄帮福2   

  1. (1.云南天朗节能环保集团有限公司,云南 安宁 65032:2.昆明理工大学冶金与能源工程学院,云南 昆明 650093)
  • 收稿日期:2022-06-09 出版日期:2022-08-30 发布日期:2023-11-29
  • 作者简介:李 锐 (1973-),男,云南昆明人,正高级工程师,主要从事钢铁烧结烟气脱硫脱硝研究。
  • 基金资助:
    安宁市科技计划项目:氨法脱硫与臭氧脱联合新工艺关键控制技术研究 (安科技字 2019(07)号);云南省应用基础研究计划面上项目:SO2对 MnOx-CeO2/AC脱硝催氏剂毒化机理研究 (202001AT070029);钢铁冶金及资源利用省部共建教育部重点实验室开放基金:转炉煤气用于 Cu/AC催化剂低温脱硝机理研究 (FM-RUlab-20-4)。

Effect of Calcium Desulfurization Wastewateron Ammonium Sulfate Crystallization

LI Rui1,ZHAO Peng1,ZHANG Yanling1,ZHOU Weibo1,HUANG Bangfu2   

  1. (1. Yunnan Tianlang Energy Saving & Environmental Protection Group Co. , ltd. , Anning, 650302, Yunnan, China;Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology , Kunming 650093, China)
  • Received:2022-06-09 Online:2022-08-30 Published:2023-11-29

摘要: 为充分发挥烧结烟气氨法脱硫系统优势回收利用钙法脱硫废水,向硫酸较母液中添加不同体积的 K 钢厂本部和二期钙法脱硫废水,研究了不同添加条件对硫酸铰晶体结晶量、粒径分布、C.V.值和形貌的影响结果表明:随废水添加量增加,硫酸铁母液结晶量随之增加,废水中的硫酸根离子和悬浮物会使硫酸铁结晶量增加。添加钙法脱硫废水后硫酸钱晶体平均粒径和 C.V,值呈不规则变化,晶体形貌总体比原母液结晶晶体更均匀,颗粒尺寸相对较大。相关研究成果可为烧结烟气钙法脱硫废水循环利用提供新思路。

关键词: 钙法脱硫, 废水, 氨法脱硫, 硫酸钱, 结晶影响

Abstract: In order to give full play to the advantages of the sintering flue gas ammonia desulfurizationsystem to recycle the calcium desulfurization wastewater, this paper adds different volumes of the mainand second-stage calcium desulfurization wastewater to the ammonium sulfate mother liquor. The efectsof different addition conditions on the crystallinity , particle size distribution, C. V. value and morpholo-gy of ammonium sulfate crystals were studied. The following conclusions are obtained. With the increasein the amount of wastewater added, the crystallization amount of ammonium sulfate mother liquor increa-Sulfate ions and suspended solids in wastewater will increase the amount of ammonium sulfate crys-ses.tals. The average particle size and C. V. value of ammonium sulfate crystals changed irregularly afterthe addition of calcium desulfurization wastewater. The crystal morphology was generally more uniformthan that of the original mother liquor, and the particle size was relatively larger. Relevant research re-sults can provide new ideas for recycling of sintered flue gas calcium desulfurization wastewater.

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