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Journal of Kunming Metallurgy College ›› 2020, Vol. 36 ›› Issue (1): 12-.DOI: 10.3969/j.issn.1009-0479.2020.01.003

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Selection and Optimization of Measuring Conditions for Determination of Indium in High-iron Sphalerite by Flame Atomic Absorption Spectrometry

LI Li,WANG Jinliang,DU Zhonglin,NING Mencui,WU Wenbin   

  1. (1. Department of Environmental and Chemical Engineering, Kunming Metallurgy College , Kunming 650033, China;2. Yunnan Tin Croup Wenshan Zinc Indium Smelting Co. , Ltd., Maguan 663701, Yunnan, China)
  • Received:2020-03-01 Online:2020-02-14 Published:2023-12-15

Abstract: The composition of high-speed iron sphalerite is complex, and there are many interference fac-tors in the determination of low-content indium. The paper made a study of the experimental conditions olthe instrument working conditions , acid medium and its concentration , etc. for the determination of indium content in high iron content sphalerite by flame atomic absorption spectrometry. The research resultsshow that at a wavelength of 303. 94 nm , an air-acetylene flame , a burner slit length of 100 mm , a widthof 0. 4 mm, and a test solution injection volume of 6mL / min , the optimal working conditions of the in-strument are: lamp current 5 A; burner height 7 cm; acetylene flow rate 1.8 ~ 2.0 L / min: air flowrate 6. 0L / min; the best acidic medium for the sample to be tested is nitric acid medium with concen-tration ( V / V)% =10% .

Key words: flame atomic absorption method, high iron content sphalerite, indium, measurement conditions

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