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昆明冶金高等专科学校学报 ›› 2021, Vol. 37 ›› Issue (5): 1-.DOI: 10.3969/j.issn.1009-0479.2021.05.001

• 冶金技术与材料 •    下一篇

氯化法 TiCl氧化制备 TiO2 中气体混合研究

李亚东1a,2,3, 孙 应1b, 程 涌1a,2, 张金梁1a,2,3, 黄 卉1a,2,3, 刘振楠1a,2,3   

  1. 1.昆明冶金高等专科学校a.冶金与矿业学院; b.科学技术处,云南昆明650033;2.昆明市稀散及贵金属资源综合利用重点实验室,云南昆明650033 ;3.稀散及贵金属二次资源综合回收及深加工应用技术协同创新中心,云南昆明650033

  • 收稿日期:2021-05-31 出版日期:2021-10-31 发布日期:2023-08-29
  • 通讯作者: 李亚东(1989-),男,甘肃甘谷人,讲师,工学博士,主要从事流体力学、量子化学、冶金工程过程仿真模拟及有色金属提取冶金与冶金物理化学研究。
  • 基金资助:
    云南省教育厅科学研究基金项目:氯化钛白氧化反应器内气相氧化过程成核结晶机理研究(2020J0766);昆明冶金高等专科学校引进人才项目:四氯化钛瞬态反应器设计及物料混合机制研究(Xxrcxm201901)。

The Study on Gas Mixing of Titania Formation by TiCl4 Gas-Phase Oxidation in Chloride Process

Ll Yadong1a,2,3, SUN Ying1b, CHENG Yong1a,2, ZHANG Jinliang1a,2,3, HUANG Hui1a,2,3, LIU Zhennan1a,2,3   

  1. 1 a. Faculty of Metallurgy and Mining Eingincering; b. Science and 'Technology Department ,Kunming Metallurgy College,Kunming 650033 , China; 2.Kunming Key Laboratory of Comprehensive Utilization Resources of Rare and Precious Metals,Kunming 650033 ,China;  3.Collaborative Imnnovation Center of Comprchensive Recovery and Deep Processing Application Technology of Rare and Precious Metal Secondary Resources,Kunming 650033 ,China

  • Received:2021-05-31 Online:2021-10-31 Published:2023-08-29

摘要: 氯化法钛白生产中的核心技术是TiCl4气相氧化反应过程。氧化反应器是氯化法钛白生产中的核心设备,氧化反应器中射流环的开孔结构直接影响TiCl4与O2 的混合效果。采用计算流体力学(CFD) 的方法,研究了5种不同射流环结构对流体混合效果的影响,获得了TiCl4气体在反应管内的径向浓度分布情况,以及TiCl4与O2混合的不均匀度。结果表明,射流环开孔结构对物料的混合有显著的影响,组合开孔射流环的物料混合效果优于均匀开孔射流环,更有利于反应物流体TiCl4和O2实现快速均匀地混合。

Abstract: The core technology in the production of titanium dioxide by chlorination is the gas phase oxi-dation of 'TiCl Oxidation reactor is the core equipment in the production of titanium dioxide by chlorina-tion method. The opening structure of jet ring in oxidation reactor directly affects the mixing effect ofTiCl and 0,. This paper adopt computational fluid dynamics ( CFD ) method to research the effects offive different jet ring structures on fluid mixing.'The radial concentration distribution of 'TiCl, gas in thereaction tube and the non-unifomity of 'TliCl and 0,mixing could be obtained.The results show that theopening stnucture of the jet ring has a significant impact on the material mixing. The material mixingeffect of the combined opening jet ring is better than that of the uniform opening jet ring,which is moreconducive to the rapid and uniform mixing of TiCl,and o,.


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