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昆明冶金高等专科学校学报 ›› 2020, Vol. 36 ›› Issue (1): 12-.DOI: 10.3969/j.issn.1009-0479.2020.01.003

• 冶金技术与材料 • 上一篇    下一篇

火焰原子吸收法测定高铁闪锌矿中铟含量的测量条件选择与优化

李 理,王锦亮,杜重麟,宁门翠,吴文彬   

  1. 1.昆明冶金高等专科学校环境与化工学院,云南昆明 650033;2.云锡集团文山锌冶炼有限公司,云南马关 663701)
  • 收稿日期:2020-03-01 出版日期:2020-02-14 发布日期:2023-12-15
  • 作者简介:李 理 (1979-),男,云南石屏人,副教授,工学硕士,主要从事环境检测与污染治理技术研究

Selection and Optimization of Measuring Conditions for Determination of Indium in High-iron Sphalerite by Flame Atomic Absorption Spectrometry

LI Li,WANG Jinliang,DU Zhonglin,NING Mencui,WU Wenbin   

  1. (1. Department of Environmental and Chemical Engineering, Kunming Metallurgy College , Kunming 650033, China;2. Yunnan Tin Croup Wenshan Zinc Indium Smelting Co. , Ltd., Maguan 663701, Yunnan, China)
  • Received:2020-03-01 Online:2020-02-14 Published:2023-12-15

摘要: 针对高铁闪锌矿组成复杂、矿石中低含量的测定干扰因素多的情况,对火焰原子吸收光谱法测定高铁闪锌矿中钢含量的仪器工作条件、酸性介质及其浓度等影响因素进行了试验研究。结果表明:在波长为 303.94nm,采用空气-乙快火焰,燃烧器狭缝长度为100 mm、宽度为0.4mm,试液进样量6 m/min 的情况下,仪器最佳工作条件为:灯电流5 mA: 燃烧器高度7cm,乙快流量1.8~2.0L/min,空气流量6.01/min,待测样品最佳酸性介质为体积分数为 10% 的硝酸介质。

关键词: 火焰原子吸收法, 高铁闪锌矿, 铟, 测量条件

Abstract: The composition of high-speed iron sphalerite is complex, and there are many interference fac-tors in the determination of low-content indium. The paper made a study of the experimental conditions olthe instrument working conditions , acid medium and its concentration , etc. for the determination of indium content in high iron content sphalerite by flame atomic absorption spectrometry. The research resultsshow that at a wavelength of 303. 94 nm , an air-acetylene flame , a burner slit length of 100 mm , a widthof 0. 4 mm, and a test solution injection volume of 6mL / min , the optimal working conditions of the in-strument are: lamp current 5 A; burner height 7 cm; acetylene flow rate 1.8 ~ 2.0 L / min: air flowrate 6. 0L / min; the best acidic medium for the sample to be tested is nitric acid medium with concen-tration ( V / V)% =10% .

Key words: flame atomic absorption method, high iron content sphalerite, indium, measurement conditions

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