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昆明冶金高等专科学校学报 ›› 2023, Vol. 39 ›› Issue (2): 10-.DOI: 10.3969/j.issn.1009-0479.2023.02.002

• 冶金技术与材料 • 上一篇    下一篇

含氧化钛三元熔渣体系组元活度的预测

孙 应1a ,刘振楠1b,2 ,张凇源1a,2 ,刘 聪1b
  

  1. (1.昆明冶金高等专科学校 a科学技术处;b冶金与矿业学院,云南 昆明 650033;2.昆明市稀散及贵金属资源综合利用重点实验室,云南 昆明 650033)
  • 收稿日期:2023-06-20 出版日期:2023-04-30 发布日期:2023-11-10
  • 作者简介:孙应 (1987-),男,贵州毕节人,工学硕士,讲师,主要从事冶金熔体热力学研究。
  • 基金资助:
    云南省教育厅科学研究基金资助项目:转炉提钒过程中钒的热力学行为研究 (2022J1032);CoCrFeNi-X系高熵合金的热力学研究 (2022J1303);昆明冶金高等专科学校校级科研基金项目:钒钛磁铁矿高炉冶炼过程中 Ti元素在渣 -铁间的平衡分配研究 (2021XJZK04)。

Prediction of component activities in the ternary molten slags containing titanium oxide

SUN Ying, LIU Zhennan, ZHANG Songyuan, LI U Cong

  

  1.  (1a.Science and Technology Department;  b.  Faculty of Metallurgy and Mining,  Kunming Metallurgy College,Kunming 650033,China; 2. Kunming Key Laboratory of Comprehensive Utilization Resources of Rare and Precious Metals,  Kunming 650033,China)

  • Received:2023-06-20 Online:2023-04-30 Published:2023-11-10

摘要:

分别应用分子相互作用体积模型 (MIVM)伪多元法和共存理论作用浓度模型对 FeO-MnO-TiO2、FeO-MnO-SiO2、MnO-SiO2-TiO2以及 FeO-SiO2-TiO2等渣系中组元 FeO或 MnO的活度进行了预测,对比实验值的误差显示:MIVM伪多元法预测值的总平均相对误差为 16%,总平均标准偏差为 0062;共存理论预测值的总平均相对误差为 28%,总平均标准偏差为 0.077,MIVM伪多元法的预测效果相对共存理论较好,表明了 MIVM伪多元法预测熔渣体系组元活度有较好的稳定性和可靠性。应用该模型预测了 FeO-MnO-TiO2、MnO-SiO2-TiO2 以及 FeO-SiO2 -TiO2 等渣系中组元 TiO2 的活度,绘制其等活度曲线,并分析不同渣系中组元TiO2的热力学行为倾向。

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Abstract:

Based on the molecular interaction volume model(MIVM) and the coexistence theory model,the component activities were predicted in the ternary slags Fe0-Mn0-SiOz,Fe0-Mn0-TiOz,Mn0-SiOz-TiOzand Fe0-SiOz-TiOz .In com parison with the experiment data,the total average relative errors of the predicted value by pseudo-multicomponent approach of MIVM were 16%,the total average standard deviations were 0. 062. On the other hand,the total average relative errors of the predicted value by coexistence theory model were 28%,the total average standard deviations were 0.  077. The prediction effect of the pseudo-multicomponent approach of MIVM has better stability and reliability than coexistence theory. the activities of component TiOzwere predicted in the ternary slags Fe0-Mn0TiOz,Mn0-SiOz-TiOzand Fe0-SiOz-TiOz by MIVM,draw its isoactivity curve,the thermodynamic behavior tendency of constituent TiOz in different slag systems was analyzed.

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