ＳｔｕｄｙｏｎＰｒｏｃｅｓｓＰａｒａｍｅｔｅｒｓｏｆＡｓｙｍｍｅｔｒｉｃＨｙｄｒｏｇｅｎａｔｉｏｎｏｆＣａｍｐｈｏｒｂｙＮｉｃｋｅｌＯｘｉｄｅＣａｔａｌｙｓｔｕｎｄｅｒＡｔｍｏｓｐｈｅｒｉｃＰｒｅｓｓｕｒｅ

doi:10.3969/j.issn.1009-0479.2018.05.008

Abstract

Abstract: Ｃｏｎｓｉｄｅｒｉｎｇｔｈｅｈｉｇｈｈｙｄｒｏｇｅｎａｔｉｏｎａｃｔｉｖｉｔｙａｎｄａｓｙｍｍｅｔｒｉｃｓｅｌｅｃｔｉｖｉｔｙｏｆｎｉｃｋｅｌｍｅｔａｌ，ｔｈｅａｓｙｍｍｅｔｒｉｃｒｅｄｕｃｔｉｏｎｏｆｃａｍｐｈｏｒｉｎｔｏＤｂｏｒｎｅｏｌｗａｓｃａｒｒｉｅｄｏｕｔｉｎＮｉＯ／ａｌｃｏｈｏｌｓｙｓｔｅｍ．Ｃｅｒｔａｉｎｅｆｆｅｃｔｓｏｆｉｎｔｈｅｐｒｏｃｅｓｓｗｅｒｅｉｎｖｅｓｔｉｇａｔｅｄｓｕｃｈａｓｃａｍｐｈｏｒｄｏｓａｇｅ，ｃａｔａｌｙｓｔａｍｏｕｎｔ，ｒｅａｃｔｉｏｎｔｉｍｅ，ｒｅａｃｔｉｏｎｔｅｍｐｅｒａｔｕｒｅａｎｄｐｏｔａｓｓｉｕｍｈｙｄｒｏｘｉｄｅ／ｓｏｄｉｕｍｂｒｏｍｉｄｅｄｏｓａｇｅｏｎｔｈｅｙｉｅｌｄｏｆｂｏｒｎｅｏｌ．Ｔｈｅｅｘｐｅｒｉｍｅｎｔａｌｒｅｕｌｔｓｉｎｄｉｃａｔｅｄｔｈａｔｏｎｔｈｅｏｐｔｉｍａｌｒｅａｃｔｉｏｎｃｏｎｄｉｔｉｏｎ，ｔｈｅＤｂｏｒｎｅｏｌｐｒｏｄｕｃｅｄｒｅａｃｈｅｄｔｈｅｈｉｇｈｅｓｔｉｎＮｉＯ／ａｌｃｏｈｏｌｓｙｓｔｅｍｗｈｅｎｔｈｅｃａｔａｌｙｓｔａｍｏｕｎｔｉｓ５２ｍｍｏｌ，ｔｈｅｃａｍｐｈｏｒｄｏｓａｇｅｉｓ６６ｍｍｏｌ，ｒｅａｃｔｉｏｎｔｅｍｐｅｒａｔｕｒｅｉｓ５０℃，ｒｅａｃｔｉｏｎｔｉｍｅｉｓ５ｈ，ａｎｄｐｏｔａｓｓｉｕｍｈｙｄｒｏｘｉｄｅ／ｓｏｄｉｕｍｂｒｏｍｉｄｅｄｏｓａｇｅａｒｅｉｎｔｈｅｍｏｌｅｐｒｏｐｏｒｔｉｏｎｏｆ１２８∶１．

Key words: ａｓｙｍｍｅｔｒｙｓｙｎｔｈｅｔｉｚｉｎｇ, ｃａｍｐｈｏｒ, Ｄｂｏｒｎｅｏｌ, ＮｉＯ, Ｈ２

CLC Number:

ＴＱ０１６

ＺＨＡＮＧＲｕｎｈｕａ, ＬＩＬｉｂ, ＮＩＮＧＭｅｎｃｕｉ. ＳｔｕｄｙｏｎＰｒｏｃｅｓｓＰａｒａｍｅｔｅｒｓｏｆＡｓｙｍｍｅｔｒｉｃＨｙｄｒｏｇｅｎａｔｉｏｎｏｆＣａｍｐｈｏｒｂｙＮｉｃｋｅｌＯｘｉｄｅＣａｔａｌｙｓｔｕｎｄｅｒＡｔｍｏｓｐｈｅｒｉｃＰｒｅｓｓｕｒｅ[J]. HPMug2oMmNrOfxWQHLiEksa6s0hFu9Ox348d7QefarYlaFR5ArkhOwm3Da1pmxmxCtenj1+6luWD#r#n+EPn9L6Ce+9onqnMlT+i, DOI: 10.3969/j.issn.1009-0479.2018.05.008.

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